Difference between Stainless Steel and Duplex Stainless Steel

 

What Is The Difference Between Stainless Steel And Duplex Stainless Steel

stainless steel is a name given to any steel that is stainless. To qualify as stainless, the material must have a minimum of 10% chromium in the content. There are ferritic and austenitic stainless steel grades. These come in the 400 series and 300 series respectively. The ferritic steels are magnetic and the austenitic steels are non-magnetic. They have different metallurgic microstructures. The duplex steels have both ferritic and austenitic phases in the metallurgic microstructure and have the best of both ferritic and austenitic steel grades together. The duplex steels are both strong and corrosion resistance. The modern duplex grades are used in place of more traditional and expensive metal material. There are three major categories of duplex steel such as standard duplex, super duplex and lean duplex grades.

Galvanic Corrosion Between Stainless Steel And Duplex Stainless Steel

The stainless steels can handle corrosion to certain extent but not very good at handling highly corrosive agents. Grades such as the 316 austenitic stainless steels can handle high concentrations of chlorides but cannot handle acids. The duplex grades have better corrosion resistance to chlorides, acids, reducing agents and oxidizing agents. The corrosion resistance of the different duplex grades is better than most austenitic stainless steels. In extremely corrosive applications such as acid production plants, much versatile materials such as the hastelloys are used.


Pickling And Passivation Of Duplex And Stainless Steel

The pickling and passivation processes improve the corrosion resistance or materials. The pickling method involves the surface treatment of any metal to remove impurities. The removal of inorganic contaminants and stains is important for pipes and tubes before being used in sensitive applications such as food grade applications and chemical applications. The passivation is a process through which the material surface is made inactive. The iron and oxides from the surface are removed by an acid bath. The passivation method is much useful for products that are to be used in acidic applications and applications with other oxidizing agents. Usually, the metals are pickled, machined and then passivated to get the best result and to fully cleanup the surface.

Advantages And Disadvantages Of Duplex And Stainless Steel

The stainless steels are definitely cheaper than the duplex grades. The stainless steels are readily available in the market and are used for many applications. They could be machined, cut, formed and welded with ease. The duplex steel grades are not readily available in the market. They have to be specified and ordered because they are not as common as the stainless steels. Also the prices of the duplex steels are higher due to the higher alloying content in the composition. The duplex steel grades have specific welding procedures such as preheating to a definite temperature before welding and post weld heat treating after welding. However, for applications that require strength, corrosion resistance and high temperature resistance, regardless of the higher prices, the duplex steels are much suitable.

 

Chemical composition of Duplex stainless steel grades
EUROPE EN BRITISH BS AISI DIN SS TYPICAL COMPOSITION (%)
C CR NI MO OTHER
1.4362 X2CrNiN23-4 2327 0.03 × 22 4 0.4 0.4 Cu
1.4410 2328 0.03 × 24 6 3
1.4460 329 X4CrNiMoN27-5-2 2324 0.05 × 25 5 1.5
1.4462 X2CrNiMoN22-5-3 2377 0.03 × 22 5 3
1.4501 318S13 0.03 × 24 6 3 0.5 W
1.4507 0.03 × 24 6 3 1.0 Cu

 

Duplex Steel weldability
  • Gas tungsten arc welding TIG
  • Submerged arc welding
  • Plasma arc welding
  • Shielded metal arc welding
  • Resistance welding
  • Laser welding
  • Flux-cored arc welding
  • High-frequence welding
  • Gas metal arc welding MIG

 

Duplex Steel Grades
DUPLEX TYPE PREN
Standard Approximately 35
Lean 25-30
Duplex Above 40

 

Use the following comparison tool while choosing a material:
  AUSTENITIC STAINLESS STEEL FERRITIC STAINLESS STEEL MARTENSITIC STAINLESS STEEL DUPLEX STEEL
Formability M/H L/M L L/M
Oxide Resistance M H - M
Weldability M/H M/H L M
Toughness H L/M M M
Room Temp. Strength M/H M VH H
Corrosion Resistance H M/H M M/H
Strength at Temperature H L/M - H
Price Comparison H M M H

 

Physical properties of Duplex and Stainless Steel
GRADES TEMPERATURE YOUNG'S MODULUS THERMAL EXPANSION COEFFICIENT SPECIFIC HEAT CAPACITY THERMAL CONDUCTIVITY
C F GPA 10−6K1 J KG−1 K−1 WM−1 K−1
Ferritic A516* 20 68 205 12.5 450 60
S43000 20 68 205 10 480 22
S44700 20 68 205 10 480 21
Auslenitic S30400 20 68 205 16 520 16
N08904 20 68 205 16 544 15
Duplex S31803 20 68 200 470 14
100 212 190 13 500 15
200 392 180 14 530 17
300 572 170 14.5 560 18
S32304 20 68 200 13 470 16
Superduplex S32750 20 68 200 13 470 14
S32760 20 68 190 12.8 482 12.9
S32520 20 68 205 13.5 450 17
100 212 195 14 500 18
200 392 185 14.5 530 19

 

4 Types of Stainless steel
  • Duplex Steel
  • Austenitic
  • Ferritic
  • Martensitic

Duplex stainless Steel:

  • 2205: Heat exchangers and pressure vessels
  • 2507: Pressure vessels and desalination plants

Austenitic Stainless Steel:

  • Grade 309
  • Grade 304
  • Grade 303
  • Grade 304L
  • Grade 316L
  • Grade 316

Precipitation Hardened Stainless Steel:

  • 15-5 PH
  • 17-4 PH

Martensitic Stainless Steel:

  • Grade 440C
  • Grade 410

Ferritic Stainless Steel:

  • Grade 439
  • Grade 416
  • Grade 409
  • Grade 430